Near-Stoichiometric Adsorption of Phosphate by Silica Gel Supported Nanosized Hematite
نویسندگان
چکیده
منابع مشابه
Sonochemical synthesis of nanosized hollow hematite.
Hollow inorganic materials are of great interest, in part because of their diverse applications for drug delivery, catalysis, photonic crystals, etc.1 Various preparation methods have been developed to fabricate hollow inorganic materials2,3 and even hollow single crystals;4 most commonly these synthetic methods exploit the use of silica nanospheres as a sacrificial template material. While sil...
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A mathematical model describing the behaviors of current commercialized silica gel-water adsorption chillers is presented in this study. Comparing with the previous study, this model comprises (i) a realistic representation of the thermal mass of the associated piping materials and fins; (ii) a distributed modeling of the reactor bed for the sorption processes. The model is demonstrated on a tw...
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Treatment under H2 at 300 °C of Ru(COD)(COT) dispersed on silica yields 2 nm ruthenium nanoparticles, [Rup/SiO2], according to EXAFS, HRTEM and XPS. H2 adsorption measurements on [Rup/SiO2] in the absence of O2 show that Ru particles adsorb up to ca. 2 H per surface ruthenium atoms (2H/Rus) on various samples; this technique can therefore be used to measure the dispersion of Ru particles. In co...
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A series of imidazolium and pyridinium ionic liquids with different anions (Cl(-), Br(-), BF₄(-), PF₆(-)) has been evaluated for their adsorption activity on silica gel. Quantification of the ionic liquids has been performed by the use of RP-HPLC with organic-aqueous eluents containing an acidic buffer and a chaotropic salt. Pseudo-second order kinetic models were applied to the experimental da...
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Phosphate, 3 - 10 nmol, in 1 dm3 of natural-water samples was quantitatively collected along with 10 micromol of Fe(III) ion onto a silica-gel collector in the pH range of 5.4 - 6.2. The amount of Fe(III) ion needed was limited to such a low level that the Pyrocatechol Violet method could be applied without removing the Fe(III) ion, providing a superior determination method for phosphate. Surfa...
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ژورنال
عنوان ژورنال: ISRN Inorganic Chemistry
سال: 2013
ISSN: 2314-470X
DOI: 10.1155/2013/969746